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Mixture.Not applicable.TSCA 8(b) inventory: Water; TrimethylamineNot available.Not available.Trimethylamine 28% Aqueous SolutionNot applicable.Not available.Not applicable.
NameCAS #% by Weight
Water7732-18-572
Trimethylamine75-50-328
Trimethylamine: ORAL (LD50): Acute: 500 mg/kg [Rat].
Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, . Hazardous in case of skin contact (corrosive), of eye contact (corrosive). Non-corrosive for lungs. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection.
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately.In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical attention.If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or corrosive. Seek medical attention.Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband.Not available.
Flammable.Not available.OPEN CUP: 3.3°C (37.9°F).LOWER: 2% UPPER: 11.6%These products are carbon oxides (CO, CO2).Highly flammable in presence of open flames and sparks, of heat. Non-flammable in presence of shocks, of oxidizing materials, of reducing materials, of combustible materials, of organic materials, of metals, of acids, of alkalis.Non-explosive in presence of open flames and sparks, of shocks.Flammable liquid, soluble or dispersed in water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use alcohol foam, water spray or fog. Cool containing vessels with water jet in order to prevent pressure build-up, autoignition or explosion.FLAMMABLE.Potentially explosive reaction with bromine + heat, ethylene oxide, triethynyl-aluminum (Trimethylamine)
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.Flammable liquid. Corrosive liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.
Keep container dry. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes.Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame). Do not store above 6°C (42.8°F). Refrigerate
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.Face shield. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Boots.Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.Trimethylamine TWA: 10 STEL: 15 (ppm) from OSHA (PEL) [United States] TWA: 5 STEL: 15 (ppm) from ACGIH (TLV) [United States] TWA: 2.4 (mg/m3) from AIHA [United States] TWA: 1 (ppm) from AIHA [United States] TWA: 24 STEL: 36 (mg/m3) from OSHA (PEL) [United States]Consult local authorities for acceptable exposure limits.
Liquid.Ammoniacal. Fish.Not available.Not applicable.Colorless.Not available.40°C (104°F) - 50 CNot available.Not available.0.83 - 0.93(Water = 1)46.1 kPa (@ 20°C)2.04 (Air = 1)Not available.Not available.Not available.Not available.See solubility in water, diethyl ether.Easily soluble in cold water, hot water. Soluble in diethyl ether.
The product is stable.Not available.Heat, ignition sources, incompatible materialsSlightly reactive to reactive with oxidizing agents, acids.Non-corrosive in presence of glass.Incompatible with ethylene oxide, bromine, nitrosating agents (sodium nitrate), chlorine, reactive organic compounds, some metals, mercury.Corrosive to many metals (zinc, brass, aluminum, copper). (Trimethylamine)Will not occur.
Absorbed through skin. Eye contact. Inhalation. Ingestion.Acute oral toxicity (LD50): 2083 mg/kg (Rat) (Calculated value for the mixture).Not available.Very hazardous in case of skin contact (irritant), of ingestion, . Hazardous in case of skin contact (corrosive), of eye contact (corrosive), of inhalation (lung corrosive).Lowest Published Lethal Dose: LDL[Rat] - Route: Inhalation; Dose 3500 ppm/4 hours (Trimethylamine)May cause adverse reproductive effects based on animal test dataAcute Potential Health Effects: Skin: Causes severe skin irritation and ulcerations/burns. Eyes: Causes severe irritation and burns. Contact may cause conjunctival ulceration and hemorrhages and corneal ulceration, edema and opacities. Ingestion: Harmful if swallowed. May cause severe gastrointestinal tract irritaitonand possible burns. Symptoms may include nausea, vomiting, burning sensation in the mouth, throat and stomach, pain on swallowing, swelling of the throat, profuse salivation, diarrhea, rapid breathing, risk of gastrointestinal hemorrhage, and perforation. It may affect behavior/nervous system, cardiovascular system (shock -rapid, weak pulse, cold sweat, pale complexion, lightheadness, and cold hands and feet), blood. Inhalation: May cause severe irritation of the respiratory tract with sore throat, tingling sensation in the respiratory tract, irritation of nose and eyes, coughing, shortness of breath and delayed lung edema. Inhalation may also affect behavior/central nervous system (excitement, somnolence, spasticity). Chronic Potential Health Effects: Skin: Repeated or prolonged skin contact may cause dermatitis. Inhalation: Repeated or prolonged inhalation may affect behavior/central nervous system, respiration (fibrosis, pneumoconiosis, pulmonary edema, chemical bronchitis)), and blood (changes in red blood cell count), and metabolism (weight loss), and endocrine system (adrenal gland).
Not available.Not available.Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.The products of degradation are less toxic than the product itself.Not available.
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
CLASS 3: Flammable liquid. Class 8: Corrosive material: Trimethylamine, aqueous solution UNNA: 1297 PG: IINot available.
Connecticut hazardous material survey.: Trimethylamine Illinois toxic substances disclosure to employee act: Trimethylamine Illinois chemical safety act: Trimethylamine New York release reporting list: Trimethylamine Rhode Island RTK hazardous substances: Trimethylamine Pennsylvania RTK: Trimethylamine Minnesota: Trimethylamine Massachusetts RTK: Trimethylamine Massachusetts spill list: Trimethylamine New Jersey: Trimethylamine New Jersey spill list: Trimethylamine New Jersey toxic catastrophe prevention act: Trimethylamine Louisiana spill reporting: Trimethylamine TSCA 8(b) inventory: Water; Trimethylamine CERCLA: Hazardous substances.: Trimethylamine: 100 lbs. (45.36 kg);OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).CLASS B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). CLASS E: Corrosive liquid.330330Gloves. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Face shield.
Not available.Not available.
 3 3 0 3 3 0
Mixture.Not applicable.TSCA 8(b) inventory: Water; TrimethylamineNot available.Not available.Trimethylamine 28% Aqueous SolutionNot applicable.Not available.Not applicable.
NameCAS #% by Weight
Water7732-18-572
Trimethylamine75-50-328
Trimethylamine: ORAL (LD50): Acute: 500 mg/kg [Rat].
Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, . Hazardous in case of skin contact (corrosive), of eye contact (corrosive). Non-corrosive for lungs. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection.
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately.In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical attention.If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or corrosive. Seek medical attention.Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband.Not available.
Flammable.Not available.OPEN CUP: 3.3°C (37.9°F).LOWER: 2% UPPER: 11.6%These products are carbon oxides (CO, CO2).Highly flammable in presence of open flames and sparks, of heat. Non-flammable in presence of shocks, of oxidizing materials, of reducing materials, of combustible materials, of organic materials, of metals, of acids, of alkalis.Non-explosive in presence of open flames and sparks, of shocks.Flammable liquid, soluble or dispersed in water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use alcohol foam, water spray or fog. Cool containing vessels with water jet in order to prevent pressure build-up, autoignition or explosion.FLAMMABLE.Potentially explosive reaction with bromine + heat, ethylene oxide, triethynyl-aluminum (Trimethylamine)
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.Flammable liquid. Corrosive liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.
Keep container dry. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes.Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame). Do not store above 6°C (42.8°F). Refrigerate
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.Face shield. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Boots.Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.Trimethylamine TWA: 10 STEL: 15 (ppm) from OSHA (PEL) [United States] TWA: 5 STEL: 15 (ppm) from ACGIH (TLV) [United States] TWA: 2.4 (mg/m3) from AIHA [United States] TWA: 1 (ppm) from AIHA [United States] TWA: 24 STEL: 36 (mg/m3) from OSHA (PEL) [United States]Consult local authorities for acceptable exposure limits.
Liquid.Ammoniacal. Fish.Not available.Not applicable.Colorless.Not available.40°C (104°F) - 50 CNot available.Not available.0.83 - 0.93(Water = 1)46.1 kPa (@ 20°C)2.04 (Air = 1)Not available.Not available.Not available.Not available.See solubility in water, diethyl ether.Easily soluble in cold water, hot water. Soluble in diethyl ether.
The product is stable.Not available.Heat, ignition sources, incompatible materialsSlightly reactive to reactive with oxidizing agents, acids.Non-corrosive in presence of glass.Incompatible with ethylene oxide, bromine, nitrosating agents (sodium nitrate), chlorine, reactive organic compounds, some metals, mercury.Corrosive to many metals (zinc, brass, aluminum, copper). (Trimethylamine)Will not occur.
Absorbed through skin. Eye contact. Inhalation. Ingestion.Acute oral toxicity (LD50): 2083 mg/kg (Rat) (Calculated value for the mixture).Not available.Very hazardous in case of skin contact (irritant), of ingestion, . Hazardous in case of skin contact (corrosive), of eye contact (corrosive), of inhalation (lung corrosive).Lowest Published Lethal Dose: LDL[Rat] - Route: Inhalation; Dose 3500 ppm/4 hours (Trimethylamine)May cause adverse reproductive effects based on animal test dataAcute Potential Health Effects: Skin: Causes severe skin irritation and ulcerations/burns. Eyes: Causes severe irritation and burns. Contact may cause conjunctival ulceration and hemorrhages and corneal ulceration, edema and opacities. Ingestion: Harmful if swallowed. May cause severe gastrointestinal tract irritaitonand possible burns. Symptoms may include nausea, vomiting, burning sensation in the mouth, throat and stomach, pain on swallowing, swelling of the throat, profuse salivation, diarrhea, rapid breathing, risk of gastrointestinal hemorrhage, and perforation. It may affect behavior/nervous system, cardiovascular system (shock -rapid, weak pulse, cold sweat, pale complexion, lightheadness, and cold hands and feet), blood. Inhalation: May cause severe irritation of the respiratory tract with sore throat, tingling sensation in the respiratory tract, irritation of nose and eyes, coughing, shortness of breath and delayed lung edema. Inhalation may also affect behavior/central nervous system (excitement, somnolence, spasticity). Chronic Potential Health Effects: Skin: Repeated or prolonged skin contact may cause dermatitis. Inhalation: Repeated or prolonged inhalation may affect behavior/central nervous system, respiration (fibrosis, pneumoconiosis, pulmonary edema, chemical bronchitis)), and blood (changes in red blood cell count), and metabolism (weight loss), and endocrine system (adrenal gland).
Not available.Not available.Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.The products of degradation are less toxic than the product itself.Not available.
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
CLASS 3: Flammable liquid. Class 8: Corrosive material: Trimethylamine, aqueous solution UNNA: 1297 PG: IINot available.
Connecticut hazardous material survey.: Trimethylamine Illinois toxic substances disclosure to employee act: Trimethylamine Illinois chemical safety act: Trimethylamine New York release reporting list: Trimethylamine Rhode Island RTK hazardous substances: Trimethylamine Pennsylvania RTK: Trimethylamine Minnesota: Trimethylamine Massachusetts RTK: Trimethylamine Massachusetts spill list: Trimethylamine New Jersey: Trimethylamine New Jersey spill list: Trimethylamine New Jersey toxic catastrophe prevention act: Trimethylamine Louisiana spill reporting: Trimethylamine TSCA 8(b) inventory: Water; Trimethylamine CERCLA: Hazardous substances.: Trimethylamine: 100 lbs. (45.36 kg);OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).CLASS B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). CLASS E: Corrosive liquid.330330Gloves. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Face shield.
Not available.Not available.
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